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SOLUTIONS AND COLLIGATIVE PROPERTIES



Multiple Choice
Identify the letter of the choice that best completes the statement or answers the question.
 

1. 

Which of the following is an electrolyte?
a.
sodium chloride
c.
water
b.
sugar
d.
glass
 

2. 

A substance whose water solution does NOT conduct a current is a(n)
a.
polar substance.
c.
electrolyte.
b.
nonelectrolyte.
d.
ionic substance.
 

3. 

Which of the following does NOT increase the rate of dissolving a solid in water?
a.
raising the temperature
c.
using larger pieces of solid
b.
stirring
d.
crushing the solid
 

4. 

Which of the following will dissolve most rapidly?
a.
sugar cubes in cold water
c.
powdered sugar in cold water
b.
sugar cubes in hot water
d.
powdered sugar in hot water
 

5. 

If the amount of solute present in a solution at a given temperature is less than the maximum amount that can dissolve at that temperature, the solution is said to be
a.
saturated.
c.
supersaturated.
b.
unsaturated.
d.
concentrated.
 

6. 

In a solution at equilibrium,
a.
no dissolution occurs.
b.
the rate of dissolution is less than the rate of crystallization.
c.
the rate of dissolution is greater than the rate of crystallization.
d.
the rate of dissolution and the rate of crystallization are equal.
 

7. 

The solubility of a solute depends on
a.
the nature of the solute and the temperature of the solvent.
b.
the nature of the solute only.
c.
the temperature of the solvent only.
d.
neither the nature of the solute nor the temperature of the solvent.
 

8. 

The solubility of gases in liquids
a.
always increases with increasing pressure.
b.
sometimes increases with increasing pressure.
c.
always decreases with increasing pressure.
d.
does not depend on pressure.
 

9. 

What is the molarity of a solution that contains 0.202 mol KCl in 7.98 L solution?
a.
0.0132 M
c.
0.459 M
b.
0.0253 M
d.
1.363 M
 

10. 

What is the molality of a solution that contains 5.10 mol KNO3 in 4.47 kg water?
a.
0.315 m
c.
1.02 m
b.
0.779 m
d.
1.14 m
 

11. 

How many moles of HCl are present in 0.70 L of a 0.33 M HCl solution?
a.
0.23 mol
c.
0.38 mol
b.
0.28 mol
d.
0.47 mol
 

12. 

How many milliliters water are needed to make a 0.171 M solution that contains 1.00 g of NaCl?
a.
100 mL
c.
171 mL
b.
1000 mL
d.
17.1 mL
 

13. 

A solution of sugar in water has a density of 1.05 g/cm3. If you have 75 mL of the
solution, and if the solution is 8.1% sugar, how many grams of sugar are there in the
solution?
a.
63.8 g sugar
c.
60.8 g sugar
b.
6.4 g sugar
d.
6.1 g sugar
 

14. 

What is the boiling point change for a solution containing 0.328 moles of naphthalene (a nonvolatile, nonionizing compound) in 250. g of liquid benzene?  (Kb = 2.53°C/m for benzene)
     
a.
3.32°C
c.
7.41°C
b.
1.93°C
d.
4.31°C
 

15. 


Which of the following aqueous solutions has the highest boiling point?
a.
1.0 m NaOH
c.
1.0 m Na2SO4
b.
1.0 m NH4NO3
d.
1.0 m KC2H3O2
 

16. 

What is the approximate freezing-point depression of a 0.010 m aqueous CaCl2 solution?
a.
–0.019ºC
c.
–0.056ºC
b.
–0.037ºC
d.
–0.074ºC
 

17. 

Which of the following pairs of solutions produce a precipitate when combined?
a.
KOH and NH4Cl
c.
Na2SO4 and KCl
b.
Fe(NO)3 and KCl
d.
NH4Cl and AgNO3
 

18. 

Which solute is present in aqueous solution mostly as molecules rather than as ions?
a.
a weak electrolyte
c.
a nonelectrolyte
b.
a strong electrolyte
d.
a covalent electrolyte
 

19. 

Colligative properties depend on
a.
the identity of the solute particles.
b.
the concentration of the solute particles.
c.
the physical properties of the solute particles.
d.
the boiling point and freezing point of the solution.
 

20. 

Why is vapor-pressure lowering a colligative property?
a.
It depends on the concentration of a nonelectrolyte solute and does not depend on solute identity.
b.
It depends on the concentration of an electrolyte solute and does not depend on solute identity.
c.
It depends on the concentration of a nonelectrolyte solute and on solute identity.
d.
It depends on the concentration of an electrolyte solute and on solute identity.
 

21. 

What is the approximate freezing-point depression of a 0.050 m aqueous Na2SO4 solution?
a.
–0.11ºC
c.
–0.22ºC
b.
–0.28ºC
d.
–0.39ºC
 

22. 

Compared with a 0.01 m sugar solution, a 0.01 m MgCl2 solution has
a.
the same freezing-point depression.
b.
about twice the freezing-point depression.
c.
about three times the freezing-point depression.
d.
about four times the freezing-point depression.
 

23. 

When a 20.0-g sample of an unknown compound is dissolved in 500. g of benzene, the freezing point of the resulting solution of 3.77°C.  The freezing point of pure benzene is 5.48°C and Kf for benzene is 5.12°C/m.  Calculate the molar mass of the unknown compound
a.
120. g/mol
c.
100. g/mol
b.
140. g/mol
d.
80.0 g/mol
 

Problem
 

24. 

Muriatic acid is often used to remove rust. A solution of muriatic acid, HCl, reacts with Fe2O3 deposits on industrial equipment. How many liters of 5.50 M HCl would be needed to react completely with 439 g Fe2O3?
 

25. 

Suppose you need to prepare 1000. mL of 0.100 m HCl(aq), and all you have on hand is 0.500 m HCl(aq).  What volume of the 0.500 m solution should be diluted to 1000. mL to give the desired 0.100 m HCl(aq) solution?
 



 
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