Multiple Choice
Identify the
letter of the choice that best completes the statement or answers the question.
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1.
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The
idea of arranging the elements in the periodic table according to their chemical and physical
properties is attributed to a. | Mendeleev. | c. | Bohr. | b. | Moseley. | d. | Ramsay. | | | | |
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2.
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Mendeleev noticed that properties of elements usually repeated at regular intervals
when the elements were arranged in order of increasing a. | atomic
number. | c. | reactivity. | b. | density. | d. | atomic mass. | | | | |
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3.
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Moseley's work led to the realization that elements with similar properties occurred
at regular intervals when the elements were arranged in order of increasing a. | atomic
mass. | c. | radioactivity. | b. | density. | d. | atomic number. | | | | |
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4.
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Argon, krypton, and xenon are a. | alkaline earth metals. | c. | actinides. | b. | noble
gases. | d. | lanthanides. | | | | |
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5.
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The
periodic law states that the physical and chemical properties of elements are periodic functions of
their atomic a. | masses. | c. | radii. | b. | numbers. | d. | structures. | | | | |
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6.
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In
Period 3 there are 8 elements. What sublevel(s) is (are) being filled? a. | s | c. | s and
p | b. | s and d | d. | d and f | | | | |
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7.
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Within the p-block elements, the elements at the top of the table, compared
with those at the bottom, a. | have larger radii. | c. | have lower ionization energies. | b. | are more
metallic. | d. | are less
metallic. | | | | |
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8.
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Which
orbitals are characteristic of the lanthanide elements? a. | d
orbitals | c. | f
orbitals | b. | s orbitals | d. | p orbitals | | | | |
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9.
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The
most reactive group of the nonmetals are the a. | lanthanides. | c. | halogens. | b. | transition
elements. | d. | rare-earth
elements. | | | | |
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10.
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Which
represents a neutral atom acquiring an electron in an exothermic process? a. | A +
e + energy ® A | c. | A + e ®
A + energy | b. | A + e ®
A energy | d. | A + energy ® A +
e | | | | |
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11.
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A
measure of the ability of an atom in a chemical compound to attract electrons is
called a. | electron
affinity. | c. | electronegativity. | b. | electron configuration. | d. | ionization potential. | | | | |
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12.
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Ionization energy is the energy required to remove ____ from an atom of an
element. a. | the electron
cloud | c. | an
electron | b. | the nucleus | d. | an ion | | | | |
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13.
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The
force of attraction by Group 1 metals for their valence electrons is a. | weak. | b. | zero. | c. | strong. | d. | greater than that for inner shell
electrons. | | |
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14.
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Which
response includes all the following that are properties of most metals, and no other
properties?
I. They tend to form cations.
II. They
are good heat insulators.
III. They have outer electronic shells that contain more than
four
electrons.
IV. They
tend to form ionic compounds when they combine with the
elements of Group VIIA.
a. | I, II, and
III
| c. | III and
IV
| b. | II, III, and IV
| d. | I and IV
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15.
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Which
of the following statements is false?
a. | The effective nuclear charge experienced by an electron in an
outer shell is less than the actual nuclear charge | c. | Electrons in inner shells screen, or shield, electrons in outer
shells from the full effect of the nuclear charge.
| b. | Within a family
(vertical group in the periodic table) of representative elements atomic radii increase from top to
bottom.
| d. | Transition
elements have larger atomic radii than the preceding IA and IIA elements in the same period because
transition elements have electrons in their d orbitals.
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16.
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Arrange the following elements in order of increasing atomic
radii.
K, Na, Mg, Cs, Cl
a. | Na < Mg < Cl < K <
Cs
| c. | Cs < K <
Cl < Mg < Na
| b. | Cl < Mg < Na < K <
Cs
| d. | Cl < Mg <
Cs < K < Na
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17.
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Arrange the following elements in order of increasing first ionization
energy.
Mg, Al, Si, P, S
a. | Al < Mg < Si < S <
P
| c. | Al < Mg <
Si < P < S
| b. | Mg < Al < Si < P <
S
| d. | Mg < Al <
Si < S < P
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18.
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Consider the group of ions that are isoelectronic with krypton. Which response
contains all the true statements and no others?
I.
The ion with the highest positive charge is the largest ion.
II. The
ion with the highest atomic number bears the highest positive
charge.
III. The ion
with the lowest atomic number bears the least negative
charge.
IV. The
ion with a 1+ charge is obtained by adding one electron to a
Group VIIA element.
V.
All the ions have a noble gas electronic configuration.
a. | II and III
| c. | II, IV, and V
| b. | I, II, and V
| d. | I and IV
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19.
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Which
of the following statements is true regarding sodium and potassium?
a. | Sodium has a
larger first ionization energy and a larger atomic radius
| c. | Sodium has a smaller first ionization energy and a larger
atomic radius | b. | Sodium has a larger first ionization energy and a smaller
atomic radius
| d. | Sodium has a
smaller first ionization energy and a smaller atomic radius.
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20.
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For
the following atoms the order of increasing electron affinity is:
a. | Br < Rb <
Cl < I
| c. | Rb < I <
Br < Cl
| b. | I < Rb < Cl < Br
| d. | Cl < Br < Rb < I
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21.
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With
the quantum model of the atom, scientists have come to believe that determining an electron's exact
location around the nucleus a. | is impossible. | b. | can be done
before 2005. | c. | can be done easily. | d. | can be done only
with specialized equipment. | | |
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22.
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All
of the following describe the Heisenberg uncertainly principle EXCEPT a. | it states that
it is impossible to determine simultaneously both the position and velocity of an electron or any
other particle. | b. | it is one of the fundamental principles of our present
understanding of light and matter. | c. | it helped lay the foundation for the modern quantum
theory. | d. | it helps to locate an electron in an
atom. | | |
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23.
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All
of the following describe the Schrödinger wave equation EXCEPT a. | it is an
equation that treats electrons in atoms as waves. | b. | only waves of
specific energies and frequencies provide solutions to the equation. | c. | it helped lay
the foundation for the modern quantum theory. | d. | it is similar to
Bohr's theory. | | |
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24.
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The
solutions to the Schrödinger wave equation are a. | quantum
numbers. | c. | energy
levels. | b. | wave functions. | d. | orbitals. | | | | |
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25.
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A
three-dimensional region around a nucleus where an electron may be found is called
a(n) a. | spectral
line. | c. | orbital. | b. | electron path. | d. | orbit. | | | | |
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26.
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Unlike in an orbit, in an orbital a. | an electron's position cannot be known
precisely. | b. | an electron has no energy. | c. | electrons cannot
be found. | d. | protons cannot be found. | | |
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27.
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An
electron for which n = 4 has more ____ than an electron for which n =
2. a. | spin | c. | energy | b. | stability | d. | wave nature | | | | |
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28.
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The
set of orbitals that are dumbbell-shaped and directed along the x, y, and z axes
are called a. | d
orbitals. | c. | f
orbitals. | b. | p orbitals. | d. | s orbitals. | | | | |
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29.
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An
orbital that could never exist according to the quantum description of the atom is
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30.
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For
n = 4, the number of possible orbital shapes is
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31.
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A
single orbital in the 3d level can hold ____ electrons.
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32.
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The
statement that an electron occupies the lowest available energy orbital is a. | Hund's
rule. | c. | Bohr's
law. | b. | the Aufbau
principle. | d. | the Pauli
exclusion principle. | | | | |
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33.
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"Orbitals of equal energy are each occupied by one electron before any is
occupied by a second electron, and all electrons in singly occupied orbitals must have the same
spin" is a statement of a. | the Pauli exclusion principle. | c. | the quantum effect. | b. | the Aufbau
principle. | d. | Hund's
rule. | | | | |
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34.
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In
the electron configuration for scandium (atomic number 21), what is the notation for the three
highest-energy electrons? a. | 3d1
4s2 | c. | 3d3 | b. | 4s3 | d. | 4s2
4p1 | | | | |
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35.
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The
element with electron configuration 1s2 2s2 2p6
3s2 3p2 is a. | Mg (Z = 12). | c. | S (Z = 16). | b. | C (Z =
6). | d. | Si (Z =
14). | | | | |
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36.
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The
electron notation for aluminum (atomic number 13) is a. | 1s2 2s2 2p3
3s2 3p3 3d1. | c. | 1s2 2s2
2p6 3s2 3p1. | b. | 1s2 2s2 2p6
3s2 2d1. | d. | 1s2 2s2
2p9. | | | | |
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Problem
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37.
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Use
the figure above. Which element has the following electron configuration: [Ar] 4s2
3d10 4p5?
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38.
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Use
the figure above. Which element has the following electron configuration: [Kr] 5s2
4d10 5p3?
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39.
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Use
the figure above and the symbols for the noble gases to write the electron configuration for
silicon.
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40.
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What
element's orbital diagram is shown in the figure above?
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